Browsing by Author "Chuin Hao Chin"
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Publication Improvement of Colloidal Stability in Colloidal Processing for Highly Translucent, Nanosized Zirconia(Penerbit Universiti Kebangsaan Malaysia, 2018) ;Chuin Hao Chin ;Andanastuti Muchtar ;Che Husna Azhari ;Masfueh RazaliMohamed AborasThis study aimed to improve the colloidal stability of yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) suspension through colloidal processing to obtain highly translucent Y-TZP. Agglomeration is often the main complication in the processing of nanosized Y-TZP as it deteriorates mechanical and optical properties. Thus, colloidal processing is necessary to mitigate the agglomeration in Y-TZP. The colloidal stability of Y-TZP suspension plays a key role for the success of colloidal processing. In this study, colloidal processing was conducted at several stages, namely, dispersant addition, pH adjustment and sedimentation. Changes in particle size and zeta potential at various stages were recorded. The suspensions were then slip-casted to form green bodies. Green bodies were sintered and characterized for density and translucency. The results showed that dispersant addition followed by pH adjustment effectively dispersed soft agglomerates by introducing electrosteric stabilization, whereas sedimentation successfully segregated hard agglomerates and contributed excellent colloidal stability. With high colloidal stability, the translucency of Y-TZP was improved by approximately 30%. This study demonstrated different colloidal processing stages and proved that high colloidal stability and fine particle size are vital to produce highly translucent Y-TZP. - Some of the metrics are blocked by yourconsent settings
Publication Influences Of The Processing Method And Sintering Temperature On The Translucency Of Polycrystalline Yttria-stabilized Tetragonal Zirconia For Dental Applications(Elsevier, 2018) ;Chuin Hao Chin ;Andanastuti Muchtar ;Che Husna Azhari ;Masfueh RazaliMohamed AborasThe achievement of a high esthetic value in polycrystalline yttria-stabilized tetragonal zirconia (Y-TZP)-based dental restorations is hindered by the low translucency of Y-TZP. Thus, this study investigated the effects of processing method and sintering temperature on the translucency of Y-TZP for dental applications. Wet (slip casting) and dry (cold isostatic pressing) processing methods were used. Y-TZP specimens were fabricated by applying the processing methods and sintering at different temperatures (1450�1650?�C). The mechanical, morphological, and optical properties of the Y-TZP specimens were examined and compared. The specimens were benchmarked with a commercial Y-TZP, namely, Cercon�. Results showed that wet processing produced higher mechanical properties and translucency than dry processing. This finding can be mainly attributed to the higher capability of wet processing than dry processing in alleviating the agglomeration in Y-TZP. Among the several specimens that were tested, the slip-casted Y-TZP that was sintered at 1600?�C showed the optimum mechanical properties (99.5% density and 12.7?GPa hardness) and translucency (35% light transmission) for dental applications. Furthermore, the light transmission achieved in this study was approximately three times higher than that of the commercial Y-TZP (13%), thereby indicating a potential alternative to replace the commercial Y-TZP. Highly translucent Y-TZP with excellent mechanical properties was developed in this study through wet processing with a sintering temperature of 1600?�C. The developed Y-TZP can be an alternative to commercial products to produce a highly esthetic dental restoration.