Browsing by Author "Dawes J.M."
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Publication Dopamine sensing and measurement using threshold and spectral measurements in random lasers(OSA - The Optical Society, 2016) ;Ismail W.Z.W. ;Liu G. ;Zhang K. ;Goldys E.M. ;Dawes J.M. ;Faculty of Science and Technology ;Macquarie University ;ARC Centre of Excellence Centre for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS) ;ARC Centre of Excellence for Nanoscale Biophotonics (CNBP)Universiti Sains Islam Malaysia (USIM)We developed a novel dopamine sensing and measurement technique based on aggregation of gold nanoparticles in random lasers. Dopamine combined with copper ions triggers the aggregation of gold nanoparticles and thus affects the performance of random lasers. Dopamine sensing can be achieved using four parameters which are sensitive to the presence of dopamine, that is emission peak shift, emission linewidth, signal-to-noise ratio (peak emission intensity / noise) and random lasing threshold. The dopamine is most sensitively detected by a change in the emission linewidth with a limit of detection of 1 � 10-7 M, as well as by an increase in the lasing threshold. The dopamine concentration from 1 � 10-7 M to 1 � 10-2M can be determined by calibrating with the laser threshold. �2015 Optical Society of America. - Some of the metrics are blocked by yourconsent settings
Publication Enhancing the performance of random lasers: Effects of Localised Surface Plasmons and Resonance Energy Transfer(SciTePress, 2016) ;Dawes J.M. ;Ismail W.Z.W. ;Goldys E.M. ;Coutts D.W. ;Faculty of Science and Technology ;Macquarie University ;ARC Centre of Excellence Centre for Ultrahigh-bandwidth Devices for Optical Systems ;Universiti Sains Islam Malaysia (USIM)ARC Centre of Excellence Centre for Nanoscale BioPhotonicsWe investigate the effect of different gain media and different scattering media in random lasers. We demonstrate an increase in the emission intensity and efficiency of random lasing by incorporating gold rather than dielectric alumina nanoparticles. There is a trade-off between enhancing the random laser performance due to the localised surface plasmon resonance field effects and reduction in performance due to fluorescence quenching by the gold nanoparticles. We use fluorescence resonant energy transfer between dye molecules to extend the wavelength range of emission. � Copyright 2016 by SCITEPRESS-Science and Technology Publications, Lda. All rights reserved. - Some of the metrics are blocked by yourconsent settings
Publication Extended emission wavelength of random dye lasers by exploiting radiative and non-radiative energy transfer(Springer Verlag, 2016) ;Wan Ismail W.Z. ;Goldys E.M. ;Dawes J.M. ;Macquarie University ;ARC Centre of Excellence for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS)Universiti Sains Islam Malaysia (USIM)We demonstrate long-wavelength operation (>700�nm) of random dye lasers (using a methylene blue dye) with the addition of rhodamine 6G and titania, enabled by radiative and non-radiative energy transfer. The pump energy is efficiently absorbed and transferred to the acceptors, to support lasing in random dye lasers in the near infrared. The optimum random laser performance with the highest emission intensity and the lowest lasing threshold was achieved for a concentration of methylene blue as the acceptor equal to 6� the concentration of rhodamine 6G (donor). Excessive levels of methylene blue increased the lasing threshold and broadened the methylene blue emission linewidth due to dye quenching from re-absorption. This is due to competition between the donor emission and energy transfer and between absorption loss and fluorescence quenching. The radiative and non-radiative energy transfer is analyzed as a function of the acceptor concentration and pump energy density, with consideration of the spectral overlap. The dependence of the radiative and non-radiative transfer efficiency on the acceptor concentration is obtained, and the energy transfer parameters, including the radiative and non-radiative energy transfer rate constants (KR and KNR), are investigated using Stern�Volmer analysis. The analysis indicates that radiative energy transfer is the dominant energy transfer mechanism in this system. � 2016, Springer-Verlag Berlin Heidelberg. - Some of the metrics are blocked by yourconsent settings
Publication Fluorescence resonance energy transfer (FRET) in random dye lasers(Institute of Electrical and Electronics Engineers Inc., 2016) ;Ismail W.Z.W. ;Goldys E.M. ;Dawes J.M. ;Macquarie University ;ARC Centre of Excellence for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS)Universiti Sains Islam Malaysia (USIM)We demonstrate the effect of fluorescence resonance energy transfer on the emission spectra and threshold of Rhodamine 6G / methylene blue / titania random lasers. Rhodamine 6G enhances the laser emission of methylene blue at ?700 nm. � 2015 IEEE. - Some of the metrics are blocked by yourconsent settings
Publication Plasmonic enhancement of Rhodamine dye random lasers(Institute of Physics Publishing, 2015) ;Ismail W.Z.W. ;Vo T.P. ;Goldys E.M. ;Dawes J.M. ;Faculty of Science and Technology ;Macquarie University ;ARC Centre of Excellence Centre for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS)Universiti Sains Islam Malaysia (USIM)We demonstrate improved characteristics in Rhodamine dye random lasers with the addition of gold nanoparticles. As a result of the strong plasmonic enhancement induced by gold nanoparticles, Rhodamine 640/gold random lasers have less than half the lasing threshold compared with Rhodamine 640/alumina random lasers in the weakly scattering regime for 10-3 M dye concentration. The optimum concentration of gold nanoparticles occurs at ?8 � 1010 cm-3, close to the transition between the weakly scattering and diffusive regimes. Rhodamine 640 has a better performance compared with Rhodamine 6G which is attributed to the greater spectral overlap of the Rhodamine 6G fluorescence spectrum with the plasmon resonance of gold, leading to an increased energy transfer and fluorescence quenching for Rhodamine 6G by gold. We also observe the contrasting trends of lasing threshold between random dye lasers incorporating dielectric and metal nanoparticles in the diffusive scattering regime. The effects of gold nanoparticles in random dye lasers are discussed in the context of the tradeoff between local field enhancement and fluorescence quenching. � 2015 Astro Ltd. - Some of the metrics are blocked by yourconsent settings
Publication Random laser in a fibre: Guiding and scattering contribute to reduced threshold(OSA - The Optical Society, 2016) ;Hurot C. ;Ismail W.Z.W. ;Dawes J.M. ;Faculty of Science and Technology ;Macquarie University ;36 Avenue Guy de CollongueUniversiti Sains Islam Malaysia (USIM)A random laser is demonstrated in a hollow-core photonic-crystal optical fibre, with dye solution and dielectric or metallic nanoparticles. The threshold is significantly reduced compared with the bulk solution due to optical guiding and scattering. � OSA 2016. - Some of the metrics are blocked by yourconsent settings
Publication Spectral and coherence signatures of threshold in random lasers(Institute of Physics Publishing, 2014) ;W.Z. Wan Ismail ;Liu D. ;Clement S. ;Coutts D.W. ;Goldys E.M. ;Dawes J.M. ;Faculty of Science and Technology ;Macquarie University ;ARC Centre of Excellence Centre for Ultrahigh Bandwidth Devices for Optical Systems (CUDOS)Universiti Sains Islam Malaysia (USIM)We investigated the spectral and coherence signatures of threshold in random lasers with incoherent feedback consisting of alumina colloidal nanoparticles suspended in rhodamine 6G methanol solution under nanosecond-pulsewidth pumping, based on measurement of temporal and spatial coherence properties and comparison with emission spectra. Feedback in this random laser was provided by multiple scattering from the alumina particles, and the effects of particle concentration and scattering length were studied for the weakly scattering and diffusive scattering regimes. At threshold, in each regime, the visibility of the interference fringes jumped abruptly, coinciding with a substantial increase in peak emission intensity and decrease in the linewidth of a single dominant emission peak. � 2014 IOP Publishing Ltd.