Laser-induced breakdown spectroscopy (LIBS) has been applied to perform elemental analysis of printing ink samples. Samples of black printing inks from three types of printers viz. inkjet, laser-jet, and photocopier (three different brands for each type) and one control sample (blank white A4 paper) were analysed under optimised conditions. Results revealed that the LIBS method when coupled with PCA was able to provide discriminative evidence on elemental differences among all the different printing inks. Considering its time and cost effectiveness as well as requiring only minute amount of sample with no sample pre-treatment steps, the combination of LIBS and PCA may prove useful for forensic questioned document practical caseworks. � 2019 Author(s).