The nobility of solid polymer electrolyte (SPEs) has made them a subject of interest, especially in the arena of science and technology, and most importantly as they are used as separators in industries and by researchers for the assembly of some “few battery types” and supercapacitors. This paper, highlights the nobility of the hybrid solid polymer electrolyte (HSPE), particularly at room temperature such that, it can be used as an electrolyte as well as a separator in supercapacitor fabrication. The hybrid SPEs were produced from the composition of polyvinyl alcohol (PVA) and Phosphoric acid (H3PO4), where the PVA samples were kept constant while the phosphoric acid concentration was varied at 0, 10, 20, 30, 40, 50, 60, and 70 wt. %. XRD results show that, the crystallinity decreases as the acid concentration increases and consequently, there is an enhancement in the amorphicity of the samples responsible for the process of ion transport. This characteristic behavior was confirmed by the analysis of the differential scanning calorimetry results. FESEM result pictured the entangling nature of the combined samples. High conductivity of 1.67 x 10-3. Scm-1 was recorded for the HSPE at the composition of 70:30 wt. %. It was also noticed that, the bulk modulus, Rb of the HSPE (5.73 ?) at the aforementioned composition decreases with the increase in concentration.

A separator is prepared from the resulting mixture of hybrid polymer electrolyte polyvinyl alcohol (PVA) (70%) and Phosphoric acid (H3PO4) (30%) immersed in the solution of the combination of polymethyl (methacrylate) and lauroyl chitosan (PLC), for supercapacitor application. The Electrochemical Impedance Spectroscopy (EIS) was conducted twice at normal temperature in an interval of Seven days with very high electrical conductivity of to be 6.42 × 10-4 S cm-1 and 1.84 × 10-4 S cm-1 within these intervals respectively and very low resistance. The supercapacitor was then fabricated using a Commercially Prepared Multi-walled Carbon Nanotube (CPMWCNT) which was sized to an area of 3.5 cm2 and assembled in an innovative supercapacitor tester. The result indicates a relatively high efficiency of about 90% and also exhibited long and excellent cycleability of life time (>1000 cycles) under different voltage windows.

A separator is prepared from the resulting mixture of hybrid polymer electrolyte polyvinyl alcohol (PVA) (70%) and Phosphoric acid (H3PO4) (30%) immersed in the solution of the combination of polymethyl (methacrylate) and lauroyl chitosan (PLC), for supercapacitor application. The Electrochemical Impedance Spectroscopy (EIS) was conducted twice at normal temperature in an interval of Seven days with very high electrical conductivity of to be 6.42 × 10-4 S cm-1 and 1.84 × 10-4 S cm-1 within these intervals respectively and very low resistance. The supercapacitor was then fabricated using a Commercially Prepared Multi-walled Carbon Nanotube (CPMWCNT) which was sized to an area of 3.5 cm2 and assembled in an innovative supercapacitor tester. The result indicates a relatively high efficiency of about 90% and also exhibited long and excellent cycleability of life time (>1000 cycles) under different voltage windows.