The study of chaotic motion in periodic self-excited oscillators are an area of interest in science and engineering. In the current research, a numerical solution hi backward difference form is proposed for solving these chaotic motions in periodic-self excited oscillators. Study conducted in this article focuses on chaotic motions in the form of Duffing-Van Der Pol Oscillators. A backward difference formulation in predictor-corrector (PeCe) mode is introduced for solving these Duffing-Van Der Pol directly. Numerical simulations provided will show the accuracy of the PeCe backward difference formulation.