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Synthesis, characterization and adsorption study of C-4-Phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions

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dc.FundingDetailsThe authors are grateful to the Ministry of Research, Technology and Higher Education of the Republic of Indonesia through the Research Grant Disertasi Doktor 2016 and Postgraduate Scholarship for the financial support. Our appreciation is also to Prof. Dr. Roslan Abd-Shukor of School of Applied Physics, UKM for reading through the manuscript.
dc.contributor.affiliationsUniversitas Gadjah Mada
dc.contributor.affiliationsUniversitas Jenderal Soedirman
dc.contributor.affiliationsUniversiti Sains Islam Malaysia (USIM)
dc.contributor.affiliationsFaculty of Science and Technology
dc.contributor.authorRastuti U.en_US
dc.contributor.authorSiswanta D.en_US
dc.contributor.authorPambudi W.en_US
dc.contributor.authorNurohmah B.A.en_US
dc.contributor.authorYamin B.M.en_US
dc.contributor.authorJuminaen_US
dc.date.accessioned2024-05-29T02:01:22Z
dc.date.available2024-05-29T02:01:22Z
dc.date.issued2018
dc.description.abstractC-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotometry (AAS). The effects of solution pH, contact time and initial concentration of metal ions on the adsorption capacity of CPPCR were investigated. The adsorption kinetic of all the ions obeyed the Ho and McKay pseudo 2 nd order rate law and the adsorption isotherm profile matched very well with Langmuir model. The separation factor (R L ) of CPPCR for Pb(II), Cd(II) and Cr(III) were 0.190, 0.017, and 0.065, respectively, indicating the formation of monolayer behaviour. The Gibb free energy (?G) of the adsorption for all the metal ions have negative values indicating the adsorption process of Pb(II), Cd(II) and Cr(III) by CPPCR are spontaneous.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.17576/jsm-2018-4706-12
dc.identifier.epage1179
dc.identifier.issn1266039
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85051006277
dc.identifier.spage1167
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85051006277&doi=10.17576%2fjsm-2018-4706-12&partnerID=40&md5=fce2bbb77c925d3349c4e4248ce5e287
dc.identifier.urihttps://oarep.usim.edu.my/handle/123456789/10164
dc.identifier.volume47
dc.languageEnglish
dc.language.isoen_USen_US
dc.publisherPenerbit Universiti Kebangsaan Malaysiaen_US
dc.relation.ispartofOpen Accessen_US
dc.relation.ispartofSains Malaysiana
dc.sourceScopus
dc.subject4-phenacyloxybenzaldehydeen_US
dc.subjectCalix[4]resorsinareneen_US
dc.subjectIon adsorptionen_US
dc.subjectIsotherm adsorptionen_US
dc.subjectKinetics adsorptionen_US
dc.titleSynthesis, characterization and adsorption study of C-4-Phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ionsen_US
dc.title.alternativeSains Malays.en_US
dc.typeArticleen_US
dspace.entity.typePublication

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