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Epoxidation of Cyclohexene Catalyzed by Vanadium Complex Supported on Montmorillonite K-10

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dc.contributor.authorNur Fatin Diana Che Husin,en_US
dc.contributor.authorFarah Wahida Harunen_US
dc.contributor.authorMadeeha Batoolen_US
dc.date.accessioned2024-05-28T03:37:11Z
dc.date.available2024-05-28T03:37:11Z
dc.date.issued2021
dc.date.submitted2022-1-25
dc.descriptionVol.12(9) (2021) Special Issue on the Universiti Teknologi MARA (UiTM) R&D Showcaseen_US
dc.description.abstractEpoxides are one of the important precursors for the formation of organic compounds with oxygen as they undergo ring-opening reactions easily to form bifunctional compounds. Homogeneous catalysts have been used in producing epoxide compounds. However, as these types of catalysts require further separation processes as well as corrosive issues, heterogeneous catalysts have received massive attention. In this study, natural clay from montmorillonite K10 (MMT-K10) was modified via the incorporation of VO(acac)2 at various concentrations. The result of XRD indicated that the crystalline nature of incorporated MMT-K10 was maintained with the 001 basal spacing calculated to be 9.95 Å. The AAS suggested that VO(acac)2 complex has been successfully incorporated onto MMT-K10 with the increasing amount of vanadium element as the concentration of vanadium complex solution increased. The catalytic activity of the vanadium complex supported on MMT-K10 showed that 20% of cyclohexene was converted with 70% selectivity to cyclohexene oxide using tert-butyl hydroperoxide (TBHP) as the oxidant.en_US
dc.identifier.citationHussin, N. F. D. C., Harun, F. W., and Batool, M. (2021). Epoxidation of Cyclohexene Catalyzed by Vanadium Complex Supported on Montmorillonite K-10. International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies, 12(9), 12A9H, 1-9. http://doi.org/10.14456/ITJEMAST.2021.176en_US
dc.identifier.doi10.14456/ITJEMAST.2021.176
dc.identifier.epage9
dc.identifier.issn2228-9860
dc.identifier.issue9
dc.identifier.other422-32
dc.identifier.spage1
dc.identifier.urihttps://tuengr.com/A12/12A9/12A9H.html
dc.identifier.urihttps://oarep.usim.edu.my/handle/123456789/4809
dc.identifier.volume12
dc.language.isoenen_US
dc.publisherTuEngr Groupen_US
dc.relation.ispartofInternational Transaction Journal of Engineering, Management, & Applied Sciences & Technologiesen_US
dc.subjectHeterogeneous catalysis; VO(acac)2; Alkene; Clay; MMT-K10; Tert-butyl hydroperoxide (TBHP); Gas chromatography; Cyclohexene oxide.en_US
dc.titleEpoxidation of Cyclohexene Catalyzed by Vanadium Complex Supported on Montmorillonite K-10en_US
dc.typeArticleen_US
dspace.entity.typePublication

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