Publication: Optimization of polymer inclusion membranes (PIMs) preparation for immobilization of Chrome Azurol S for optical sensing of aluminum(III)
| dc.contributor.author | Ngarisan, NI | en_US |
| dc.contributor.author | Ngah, CWZCW | en_US |
| dc.contributor.author | Ahmad, M | en_US |
| dc.contributor.author | Kuswandi, B | en_US |
| dc.date.accessioned | 2024-05-29T03:00:05Z | |
| dc.date.available | 2024-05-29T03:00:05Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Determination of Al(III) from aqueous samples using Chrome Azurol S (CAS) as reagent immobilized in polymer inclusion membranes (PIMs) was discussed. The PIMs was prepared using poly (vinyl chloride) (PVC), 2-nitrophenyl octyl ether (2-NPOE) and Aliquat 336 as polymer matrix, solvent and ion carriers respectively. Experimental designs for four factors (weight of PVC, Aliquat 336, 2-NPOE, and the concentration of CAS) were used for the optimization of the membrane fabrication. For this purpose, a two level half factorial design, which involves eight experiments, was adopted. The combination of 200 mg of PVC, 50 mg of Aliquat 336, 50 mg of 2-NPOE and 1 x 10(-3) mol/L CAS was found to be the optimum formulation for the preparation of PIMs. Wide dynamic range of Al(III) determination (0.2-50 ppm), better reproducibility within the same batch, good repeatability and photostability with RSD 1.21% and 0.93%, respectively. The calculated t values indicated that there is no significant difference between the two methods at the 95% confidence level and thus there is no bias in the method. (C) 2014 Elsevier B.V. All rights reserved. | |
| dc.identifier.doi | 10.1016/j.snb.2014.07.023 | |
| dc.identifier.epage | 470 | |
| dc.identifier.issn | 0925-4005 | |
| dc.identifier.scopus | WOS:000341455400061 | |
| dc.identifier.spage | 465 | |
| dc.identifier.uri | https://oarep.usim.edu.my/handle/123456789/11767 | |
| dc.identifier.volume | 203 | |
| dc.language | English | |
| dc.language.iso | en_US | |
| dc.publisher | Elsevier Science Sa | en_US |
| dc.relation.ispartof | Sensors And Actuators B-Chemical | |
| dc.source | Web Of Science (ISI) | |
| dc.subject | Al(III) | en_US |
| dc.subject | Polymer inclusion membrane | en_US |
| dc.subject | Chrome Azurol S | en_US |
| dc.subject | Half factorial design | en_US |
| dc.subject | Optimization | en_US |
| dc.subject | Optical sensing | en_US |
| dc.title | Optimization of polymer inclusion membranes (PIMs) preparation for immobilization of Chrome Azurol S for optical sensing of aluminum(III) | |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |