Publication:
Electrocatalytic Activities of Platinum and Palladium Catalysts for Enhancement of Direct Formic Acid Fuel Cells: An Updated Progress

dc.contributor.authorZatil Amali Che Ramlien_US
dc.contributor.authorJagadeesh Pasupuletien_US
dc.contributor.authorTengku Shafazila Tengku Saharuddinen_US
dc.contributor.authorYusra Nadzirah Yusofen_US
dc.contributor.authorWan Nor Roslam Wan Isahaken_US
dc.contributor.authorLuqmanulhakim Baharudinen_US
dc.contributor.authorChong Tak Yawen_US
dc.contributor.authorS.P. Kohen_US
dc.contributor.authorSieh Tiong Kiongen_US
dc.date.accessioned2024-05-29T02:27:05Z
dc.date.available2024-05-29T02:27:05Z
dc.date.issued2023
dc.date.submitted2023-8-16
dc.descriptionVolume 76en_US
dc.description.abstractDirect formic acid fuel cells (DFAFCs) have become an important technology and a clean energy source for various applications. However, some drawbacks in DFAFC applications, such as sluggish kinetics of formic acid oxidation (FAO) reaction at the anodic side, significantly affect DFAFC performance. An excellent catalyst, platinum (Pt), is very effective and performs excellently in FAO, but it is expensive and tends to form carbon monoxide-poisoning species on the catalyst surface. Therefore, new strategies must be developed to overcome problems related to Pt and simultaneously reduce or replace the use of Pt catalysts. This review paper covers the electrocatalytic activities of platinum and palladium (Pd)-based catalysts, which are commercial catalysts and effective for FAO and DFAFC applications. In this paper, the current progress of electrocatalyst development for anodic FAO and DFAFC applications using commercial Pt and Pd catalysts is presented, focusing on the understanding of Pt and Pd catalytic activities with the addition of alloys, metallic metals, trimetallic/tetrametallic metals, transition metals, and metal oxides. Highly potential nanostructured carbon catalyst supports (graphene-based materials, carbon nanotubes, carbon nanofibers, and graphitic carbon nitride) for FAO and DFAFC applications are also discussed. This review article also examines the literature related to Pt and Pd electrocatalysts on the synthesis routes, electrochemical conditions, and fuel cell performance within 10 years from 2013 until 2023. The challenges and strategies for electrocatalyst commercialization in the field are discussed at the end of the paper.en_US
dc.identifier.doihttps://doi.org/10.1016/j.aej.2023.06.069
dc.identifier.epage733
dc.identifier.issn1110-0168
dc.identifier.spage701
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S1110016823005434?via%3Dihub
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85164736009&origin=resultslist&sort=plf-f&src=s&sid=a3fd2b66cda087a3ddf9be2f7ccaadae&sot=b&sdt=b&s=TITLE-ABS-KEY%28Electrocatalytic+activities+of+platinum+and+palladium+catalysts+for+enhancement+of+direct+formic+acid+fuel+cells%29&sl=127&sessionSearchId=a3fd2b66cda087a3ddf9be2f7ccaadae
dc.identifier.urihttps://oarep.usim.edu.my/handle/123456789/10663
dc.identifier.volume76
dc.language.isoen_USen_US
dc.publisherElsevieren_US
dc.relation.ispartofAlexandria Engineering Journalen_US
dc.subjectDFAFC; Formic acid oxidation; Pt-based catalyst; Pd-based catalyst; CNF; CNT; Graphene; Carbon nitride; Fuel cell technology; Clean energy productionen_US
dc.titleElectrocatalytic Activities of Platinum and Palladium Catalysts for Enhancement of Direct Formic Acid Fuel Cells: An Updated Progressen_US
dc.typeArticleen_US
dspace.entity.typePublication

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