Publication:
Supercapacitor electrodes from activation of binderless green monoliths of biomass self-adhesive carbon grains composed of varying amount of graphene additive

dc.contributor.authorJasni, MRMen_US
dc.contributor.authorDeraman, Men_US
dc.contributor.authorSuleman, Men_US
dc.contributor.authorZainuddin, Zen_US
dc.contributor.authorOthman, MARen_US
dc.contributor.authorChia, CHen_US
dc.contributor.authorHashim, MAen_US
dc.date.accessioned2024-05-29T02:50:35Z
dc.date.available2024-05-29T02:50:35Z
dc.date.issued2018
dc.description.abstractBinderless electrodes of activated carbon monoliths (ACMs) and its composites with graphene are prepared by carbonization and activation of green monoliths consisting of self-adhesive carbon grains and 0-10 wt% KOH-treated graphene. Compared with ACMs, the optimized composite containing 6 wt% graphene exhibits more ordered micro-structures with increased crystallite height, and graphitic sp(2) carbons (I (D) /I (G) = 0.49 vs. 0.91) along with enhanced porosity; as revealed by X-ray diffraction, Raman, and N-2 adsorption-desorption studies. These modifications lead to increased electrical conductivity (13 vs. 9 S cm(-1)) through improved interconnections of carbon particles by graphene, and surface area similar to (800 vs. 456 m(2) g(-1)) due to increased inter-particle spacing. Further, contrary to ACMs, the composite electrodes can offer faster delivery of energy in almost 50% less response time (5 vs. 8 s) due to reduced equivalent series resistance (1.67 vs. 2.65 Omega) and charge transfer resistance (0.55 vs. 1.33 Omega).
dc.identifier.doi10.1007/s11581-017-2283-7
dc.identifier.epage1210
dc.identifier.isbn1862-0760
dc.identifier.issn0947-7047
dc.identifier.issue4
dc.identifier.scopusWOS:000428070800024
dc.identifier.spage1195
dc.identifier.urihttps://oarep.usim.edu.my/handle/123456789/11082
dc.identifier.volume24
dc.languageEnglish
dc.language.isoen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofIonics
dc.sourceWeb Of Science (ISI)
dc.subjectBinderless electrodesen_US
dc.subjectGreen monolithsen_US
dc.subjectActivated carbon monolithsen_US
dc.subjectSelf-adhesive carbon grainsen_US
dc.subjectGrapheneen_US
dc.subjectAqueous electrolyteen_US
dc.subjectEnergy storageen_US
dc.titleSupercapacitor electrodes from activation of binderless green monoliths of biomass self-adhesive carbon grains composed of varying amount of graphene additive
dc.typeArticleen_US
dspace.entity.typePublication

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