Publication:
Solid Polymer Electrolyte Production From 2-hydroxyethyl Cellulose: Effect Of Ammonium Nitrate Composition On Its Structural Properties

dc.contributor.authorM.N.Hafizaen_US
dc.contributor.authorM.I.N.Isaen_US
dc.date.accessioned2024-05-27T14:42:48Z
dc.date.available2024-05-27T14:42:48Z
dc.date.issued2017
dc.date.submitted--
dc.descriptionCarbohydrate Polymers 165 (2017) 123–131en_US
dc.description.abstractAddition of doping materials can possibly enhance the ionic conduction of solid polymer electrolyte (SPE). In this work, a new SPE using 2-hydroxyethyl cellulose (2-HEC) incorporated with different ammonium nitrate (NH4NO3) composition was prepared via solution casting method. Studies of structural proper ties were conducted to correlate the ionic conductivity of 2-HEC NH4NO3 SPE using X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. Encouraging result was obtained as the ionic conductivity increased about two orders of magnitude upon addition of 12 wt% of NH4NO3. XRD anal ysis shows the most amorphous SPE was obtained at 12-NH4NO3. From FTIR spectra, the interactions between 2-HEC and NH4NO3 were observed by the shifts of C O H peak from 1355 cm−1 to 1330 cm−1 and the presence of new N H peak in the O H region. The spectrum has been validated theoretically using Gaussian software. The results obtained from this study corroborate that the complexes of 2-HEC and NH4NO3 responsible to promote the ionic conductivity to the higher value.en_US
dc.identifier.doi10.1016/j.carbpol.2017.02.033
dc.identifier.epage131
dc.identifier.issn0144-8617
dc.identifier.issue2017
dc.identifier.other2334-18
dc.identifier.spage123
dc.identifier.urihttps://oarep.usim.edu.my/handle/123456789/3654
dc.identifier.volume165
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofCarbohydrate Polymersen_US
dc.subject2-hydroxyethyl celluloseen_US
dc.subjectAmmonium nitrateen_US
dc.subjectSolid polymer electrolyteen_US
dc.subjectAmorphous natureen_US
dc.subjectComplexationen_US
dc.subjectIonic conductivityen_US
dc.titleSolid Polymer Electrolyte Production From 2-hydroxyethyl Cellulose: Effect Of Ammonium Nitrate Composition On Its Structural Propertiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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Solid Polymer Electrolyte Production From 2-hydroxyethyl Cellulose: Effect Of Ammonium Nitrate Composition On Its Structural Properties